When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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| DATAFILE: | Cl2O_IUPAC(2007)_298K_200-500nm(rec).txt |
| NAME: | dichlorine monoxide |
| FORMULA: | Cl2O |
| AUTHOR(YEAR): | IUPAC(2007) |
| T: | 298K |
| λ: | 200-500nm(rec) |
| BIBLIOGRAPHY: |
R. Atkinson, D.L. Baulch, R.A. Cox, J.N. Crowley, R.F. Hampson, R.G. Hynes, M.E. Jenkin, M.J. Rossi, and J. Troe, "Evaluated kinetic and photochemical data for atmospheric chemistry: Volume III - gas phase reactions of inorganic halogens",
Atmos. Chem. Phys. 7, 981-1191 (2007);
DOI: 10.5194/acp-7-981-2007
|
| COMMENTS: | IUPAC(2007) recommendation: The preferred values of the absorption cross-sections between 200 and 500 nm at 298 K are an average of the data sets of H.D. Knauth, H. Alberti, and H. Clausen, "Equilibrium constant of the gas reaction Cl2O + H2O = 2 HOCl and the ultraviolet spectrum of HOCl," J. Phys. Chem. 83, 1604-1612 (1979); DOI: 10.1021/j100475a010, and C.-L. Lin, "Extinction coefficients of chlorine monoxide and chlorine heptoxide," J. Chem. Eng. Data 21, 411-413 (1976); DOI: 10.1021/je60071a030. The preferred values are in excellent agreement with the values reported by L.T. Molina and M.J. Molina, "Ultraviolet spectrum of HOCl," J. Phys. Chem. 82, 2410-2414 (1978); DOI: 10.1021/j100511a013, except for the 330-400 nm range where the values of Molina and Molina are higher |
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